Structural analysis of 1-ethyl-3-methylimidazolium bifluoride melt

被引：33

作者：

Matsumoto, K

Hagiwara, R ^{[1
]}

Ito, Y

Kohara, S

Suzuya, K

机构：

[1] Kyoto Univ, Grad Sch Energy Sci, Dept Fundamental Energy Sci, Sakyo Ku, Kyoto 6068501, Japan

[2] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan

[3] Japan Atom Energy Res Inst, Naka, Ibaraki 3191195, Japan

来源：

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS | 2003年 / 199卷

关键词：

room temperature molten salt; imidazolium; fluorohydrogenate; high-energy x-ray diffraction; liquid structure; ionic liquid;

D O I：

10.1016/S0168-583X(02)01400-3

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The structure of 1-ethyl-3-methylimidazolium bifluoride (EMImF . HF) melt has been analyzed at 333 K by a high-energy synchrotron X-ray diffraction method. The total correlation function of the EMImF . HF melt was similar to that of the solid state, indicating that not only the short range but also the intermediate-range ordering in the solid are partially preserved in the liquid state. The intra-molecular F-F correlation in the anions clearly appears in the total correlation function of the EMImF . HF melt, whereas prominent peaks are not observed in the case of a room temperature molten salt, 1-ethyl-3-methylimidazolium fluorohydrogenate. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：29 / 33

页数：5

共 13 条

[1] A THEORY OF ELECTRICAL PROPERTIES OF LIQUID METALS .3. RESISTIVITY OF BINARY ALLOYS [J].