Synthesis and optical properties of tetraethyl methano[60]fullerenediphosphonate

被引:27
作者
Cheng, FY
Yang, XL
Zhu, HS [1 ]
Song, YL
机构
[1] Beijing Inst Technol, Res Ctr Mat Sci, Beijing 100081, Peoples R China
[2] Harbin Inst Technol, Dept Phys, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
C-60; tetraethyl methylenediphosphonate; optical limiting; third-order nonlinear;
D O I
10.1016/S0040-4039(00)00491-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel C-60 organophosphonate derivative, tetraethyl methano[60]fullerenediphosphonate 2, was synthesized by the reaction of C-60 With tetraethyl methylenediphosphonate 1 in the presence of I-2 and Nail. It has high solubility in polar solvents and the nonlinear optical properties of the new compound were better than those of C-60 (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3947 / 3950
页数:4
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