Electroconductive polymer nanoparticles preparation and characterization of PANI and PEDOT nanoparticles

被引:62
作者
Oh, SG [1 ]
Im, SS [1 ]
机构
[1] Hanyang Univ, Grad Sch Adv Mat & Chem Engn, Ctr Adv Funct Polymers, Div Chem Engn, Seoul 133791, South Korea
关键词
nanoparticles; PANI; PEDOT; electrical conductivity; morphology;
D O I
10.1016/S1567-1739(02)00108-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanoparticles of electroconductive polymers were prepared in micellar solution as a polymerization medium to overcome the poor processability of electroconductive polymers. The morphologies of particles were studied through SEM and electrical conductivities of pellets formed with nanoparticles were measured by four-probe apparatus. Among many other electroconductive polymers, nanoparticles of polyaniline and poly(3,4-ethylenedioxythiophene) were prepared in anionic sodium dodecyl sulfate and dodecylbensen sulfonic acid micellar solutions. The sizes and shapes of particles were similar to those of micelles. The electrical conductivities of pellets formed with nanoparticles were 20 and 50 S/cm depending upon the polymerization conditions, which are higher values than those of pellets formed with particles prepared in bulk solutions. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:273 / 277
页数:5
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