Azides of the heavier Group 13 elements

被引：28

作者：

Müller, J ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2002年 / 235卷 / 1-2期

关键词：

azides; Group; 13; elements; chemical vapor deposition; nitrides;

D O I：

10.1016/S0010-8545(02)00181-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current knowledge about azides of the heavier Group 13 elements is reviewed. Only neutral compounds of the general formula R3-xM(N-3)(x)(D)(y) and MN3 (M = Al, Ga, In, Tl; R = organic or inorganic substituent; D = neutral donor; y = 0-3) are taken into account. The syntheses of Group 13 azides of the formal oxidation number +III can either be achieved by salt metathesis, a bond metathesis, or substitution reactions. The synthesis, structures, properties, and applications of mono-, di-, and triazides including inter- and intramolecular donor-stabilized compounds are discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：105 / 119

页数：15

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