Hot compressed water as reaction medium and reactant - Properties and synthesis reactions

被引：594

作者：

Kruse, A. ^{[1
]}

Dinjus, E. ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, Inst Tech Chem, D-76021 Karlsruhe, Germany

来源：

JOURNAL OF SUPERCRITICAL FLUIDS | 2007年 / 39卷 / 03期

关键词：

hot compressed water; supercritical water; synthesis;

D O I：

10.1016/j.supflu.2006.03.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hot compressed water (HCW, here water above 200 degrees C) possesses very interesting properties. This series of articles gives an overview of the state of the art as regards the understanding of reactions in HCW. In the first part the macroscopic and microscopic properties of HCW will be described, followed by a summary of synthesis reactions published. The impact of the unique properties shall be discussed in part II, with the thermal degradation of tert-butylbenzene and the oxidation of methanol being used as examples. The studies reported will show that the microscopic properties are of more importance to understanding reactions in HCW than assumed in the past. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：362 / 380

页数：19

共 277 条

[31] Preparation of quinolines by reduction of ortho-nitroarenes with zinc in near-critical water [J].

Boix, C ;

de la Fuente, JM ;

Poliakoff, M .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (06) :641-643

[32] ORGANOCOBALT COMPOUNDS IN THE SYNTHESIS OF PYRIDINES - AN EXAMPLE OF STRUCTURE-EFFECTIVITY RELATIONSHIPS IN HOMOGENEOUS CATALYSIS [J].

BONNEMANN, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (04) :248-262

[33] A CORRELATION BETWEEN C-13 AND CO-59 NMR DATA AND THE CATALYTIC ACTIVITY OF ORGANOCOBALT COMPLEXES IN THE SYNTHESIS OF PYRIDINE-DERIVATIVES [J].

BONNEMANN, H ;

BRIJOUX, W ;

BRINKMANN, R ;

MEURERS, W ;

MYNOTT, R ;

VONPHILIPSBORN, W ;

EGOLF, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 272 (02) :231-249

[34] Organometallic chemistry in supercritical water: metallorganic products of the CpCo-catalyzed cyclotrimerization of acetylenes [J].

Borwieck, H ;

Walter, O ;

Dinjus, E ;

Rebizant, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 570 (01) :121-127

[35] SELECTIVE DIELS-ALDER REACTIONS IN AQUEOUS-SOLUTIONS AND SUSPENSIONS [J].

BRESLOW, R ;

MAITRA, U ;

RIDEOUT, D .

TETRAHEDRON LETTERS, 1983, 24 (18) :1901-1904

[36] Geothermal vents and chemical processing: The infrared spectroscopy of hydrothermal reactions [J].

Brill, TB .

JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (19) :4343-4351

[37] Molecular dynamics simulations of aqueous NaCl solutions at high pressures and temperatures [J].

Brodholt, JP .

CHEMICAL GEOLOGY, 1998, 151 (1-4) :11-19

[38] Heterogeneously catalyzed partial oxidation of methane in supercritical water [J].

Bröll, D ;

Krämer, A ;

Vogel, H .

CHEMICAL ENGINEERING & TECHNOLOGY, 2003, 26 (07) :733-737

[39] Partial oxidation of propylene in sub- and supercritical water [J].

Bröll, D ;

Krämer, A ;

Vogel, H .

CHEMICAL ENGINEERING & TECHNOLOGY, 2003, 26 (04) :424-428

[40]

Bröll D, 2002, CHEM-ING-TECH, V74, P81

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