Selectivity in the Interaction of Electron Donor and Acceptor Molecules with Graphene and Single-Walled Carbon Nanotubes

被引：60

作者：

Varghese, Neenu ^{[1
,2
]}

Ghosh, Anupama ^{[1
,2
,3
]}

Voggu, Rakesh ^{[1
,2
]}

Ghosh, Sandeep ^{[1
,2
,3
]}

Rao, C. N. R. ^{[1
,2
,3
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, New Chem Unit, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[2] Jawaharlal Nehru Ctr Adv Sci Res, CSIR Ctr Excellence Chem, Bangalore 560064, Karnataka, India

[3] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 39期

关键词：

CHARGE-TRANSFER;

D O I：

10.1021/jp9075355

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Interaction of electron donor and acceptor molecules with graphene samples prepared by different methods as well as with single-walled carbon nanotubes (SWNTs) has been investigated by isothermal titration calorimetry (ITC). The ITC interaction energies of the graphene samples and SWNTs with electron acceptor molecules are higher than those with electron donor molecules. Thus, tetracyancethylene (TCNE) shows the highest interaction energy with both graphene and SWNTs. The interaction energy with acceptor molecules varies with the electron affinity as well as with the charge-transfer transition energy for different aromatics. Metallic SWNTs interact reversibly with electron. acceptor molecules, resulting in the opening of a gap.

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收藏

页码：16855 / 16859

页数：5

相关论文

共 26 条

[1] Structure and electronic properties of graphite nanoparticles [J].

Andersson, OE ;

Prasad, BLV ;

Sato, H ;

Enoki, T ;

Hishiyama, Y ;

Kaburagi, Y ;

Yoshikawa, M ;

Bandow, S .

PHYSICAL REVIEW B, 1998, 58 (24) :16387-16395

[2] ELECTRON AFFINITY OF ORGANIC MOLECULES [J].

BRIEGLEB, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1964, 3 (09) :617-&

[3] Binding of nucleobases with single-walled carbon nanotubes: Theory and experiment [J].

Das, Anindya ;

Sood, A. K. ;

Maiti, Prabal K. ;

Das, Mili ;

Varadarajan, R. ;

Rao, C. N. R. .

CHEMICAL PHYSICS LETTERS, 2008, 453 (4-6) :266-273

[4] Doping in carbon nanotubes probed by Raman and transport measurements [J].

Das, Anindya ;

Sood, A. K. ;

Govindaraj, A. ;

Saitta, A. Marco ;

Lazzeri, Michele ;

Mauri, Francesco ;

Rao, C. N. R. .

PHYSICAL REVIEW LETTERS, 2007, 99 (13)

[5] Changes in the electronic structure and properties of graphene induced by molecular charge-transfer [J].

Das, Barun ;

Voggu, Rakesh ;

Rout, Chandra Sekhar ;

Rao, C. N. R. .

CHEMICAL COMMUNICATIONS, 2008, (41) :5155-5157

[6] PI-COMPLEXES .2. CHARGE TRANSFER SPECTRA OF PI-COMPLEXES FORMED BY TETRACYANOETHYLENE WITH POLYCYCLIC AROMATIC HYDROCARBONS AND WITH HETEROAROMATIC BORON COMPOUNDS [J].

DEWAR, MJS ;

ROGERS, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (03) :395-&

[7] Large-scale production of single-walled carbon nanotubes by the electric-arc technique [J].

Journet, C ;

Maser, WK ;

Bernier, P ;

Loiseau, A ;

delaChapelle, ML ;

Lefrant, S ;

Deniard, P ;

Lee, R ;

Fischer, JE .

NATURE, 1997, 388 (6644) :756-758

[8] Sensing the heat: The application of isothermal titration calorimetry to thermodynamic studies of biomolecular interactions [J].

Ladbury, JE ;

Chowdhry, BZ .

CHEMISTRY & BIOLOGY, 1996, 3 (10) :791-801

[9] PI-COMPLEX INTERACTIONS BETWEEN TRINITROFLUORENONE AND POLYCYCLIC AROMATIC HYDROCARBONS [J].

LEPLEY, AR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (18) :3577-&

[10] Tuning the Electronic Structure of Graphene by Molecular Charge Transfer: A Computational Study [J].

Manna, Arun K. ;

Pati, Swapan K. .

CHEMISTRY-AN ASIAN JOURNAL, 2009, 4 (06) :855-860