Tuneable side-chain supramolecular polymer

被引：21

作者：

Cooke, Graeme

Garety, James F.

Hewage, Shanika Gunatilaka

Jordan, Brian J.

Rabani, Gouher

Rotello, Vincent M.

Woisel, Patrice

机构：

[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

[2] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

[3] Univ Sci & Technol, Lab Chim Organ & Macromol, F-59655 Villeneuve Dascq, France

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ol062846z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A random copolymer containing 1,5-dialkyloxynaphthalene moieties has been synthesized using atom-transfer radical polymerization. We have shown that this polymer has the ability to form complexes with the tetracationic cyclophane cyclobis(paraquat-p-phenylene) (CBPQT(4+)) and that electrochemical reduction of the cyclophane or the addition of a competing guest for the cavity of the cyclophane results in disassembly of the supramolecular polymer.

引用

页码：481 / 484

页数：4

共 25 条

[21]

Raymo FM, 1996, TRENDS POLYM SCI, V4, P208

[22]

Schrader T, 2005, FUNCTIONAL SYNTHETIC RECEPTORS, P1, DOI 10.1002/352760572X

[23] Self-assembly with block copolymers through metal coordination of SCS-PdII pincer complexes and pseudorotaxane formation [J].