First total synthesis and determination of the absolute configuration of strictifolione, a new 6-(ω-phenylalkenyl)-5,6-dihydro-α-pyrone, isolated from Cryptocarya strictifolia

被引：27

作者：

Juliawaty, LD

Watanabe, Y

Kitajima, M

Achmad, SA

Takayama, H

Aimi, N

机构：

[1] Chiba Univ, Grad Sch Pharmaceut Sci, Inage Ku, Chiba 2638522, Japan

[2] Inst Teknol Bandung, Dept Chem, Bandung 40132, Indonesia

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 48期

关键词：

Crytocarya; alpha-pyrone; chiral total synthesis; absolute configuration;

D O I：

10.1016/S0040-4039(02)02181-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Starting from (S)-malic acid and (S)-glycidol, the first total synthesis of strictifolione, a new 6-(omega-phenylalkenyl)-5,6-dihydro-alpha-pyrone isolated from Cryptocarya strictifolia, was accomplished, which confirmed its structure including the absolute configuration. of the asymmetric centers. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：8657 / 8660

页数：4

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[11] TOTAL SYNTHESIS OF (-)-TETRAHYDROLIPSTATIN [J].