H-1 NMR spectroscopic study of the interaction between cyclodextrins and bicyclo[3.3.1]nonanes

被引：17

作者：

Butkus, E

Martins, JC

Berg, U

机构：

[1] FREE UNIV BRUSSELS, HIGH RESOLUT NMR CTR, B-1050 BRUSSELS, BELGIUM

[2] LUND UNIV, CTR CHEM, S-22100 LUND, SWEDEN

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1996年 / 26卷 / 04期

关键词：

cyclodextrins; bicyclo[3.3.1]nonanes; complexation; NMR;

D O I：

10.1007/BF01053539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation and structure of inclusion complexes of 2,6- and 2,9-substituted bicyclo[3.3.1]nonanes with alpha- and beta-cyclodextrin (CD) has been investigated by high-resolution H-1 NMR spectroscopy. alpha- and P-CD were found to form 1:1 inclusion complexes and the binding constants were estimated from titration studies. 2D ROESY experiments provided insight into the structure of the complexes.

引用

收藏

页码：209 / 218

页数：10

相关论文

共 16 条

[1] INCLUSION-COMPOUNDS IN WATER - CALORIMETRIC AND SPECTROSCOPIC STUDIES OF THE INTERACTION OF CYCLOMALTOHEXAOSE (ALPHA-CYCLODEXTRIN) WITH ALKANOLS AT 25-DEGREES [J].

ANDINI, S ;

CASTRONUOVO, G ;

ELIA, V ;

GALLOTTA, E .

CARBOHYDRATE RESEARCH, 1991, 217 :87-97

[2]

[Anonymous], 1989, NUCL OVERHAUSER EFFE, DOI DOI 10.1002/MRC.1260280819

[3] PRACTICAL ASPECTS OF TWO-DIMENSIONAL TRANSVERSE NOE SPECTROSCOPY [J].

BAX, A ;

DAVIS, DG .

JOURNAL OF MAGNETIC RESONANCE, 1985, 63 (01) :207-213

[4] INCLUSION COMPLEX-FORMATION OF ANTHRACYCLINE ANTIBIOTICS WITH CYCLODEXTRINS - A PROTON NUCLEAR-MAGNETIC-RESONANCE AND MOLECULAR MODELING STUDY [J].

BEKERS, O ;

KETTENESVANDENBOSCH, JJ ;

VANHELDEN, SP ;

SEIJKENS, D ;

BEIJNEN, JH ;

BULT, A ;

UNDERBERG, WJM .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1991, 11 (02) :185-193

[5] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[6] DIRECT OBSERVATION AND RATE OF INTERCONVERSION OF THE 1/2-COMPLEX BETWEEN 1,4-DIMETHYLBICYCLO[2.2.2]OCTANE AND ALPHA-CYCLODEXTRIN BY NMR [J].

BERG, U ;

GUSTAVSSON, M ;

ASTROM, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (07) :2114-2115

[7] STEREOCHEMISTRY OF THE REDUCTION OF BICYCLO[3.3.1]NONANE-2,9-DIONE BY COMPLEX HYDRIDES [J].

BERG, U ;

BUTKUS, E ;

STONCIUS, A .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (01) :97-102

[8]

BISHOP R, 1988, TOP CURR CHEM, V149, P137

[9]

BUTKUS E, 1980, Z CHEM, V20, P103

[10] EFFECTS OF INTERMEDIATE EXCHANGE PROCESSES ON THE ESTIMATION OF EQUILIBRIUM-CONSTANTS BY NMR [J].

FEENEY, J ;

BATCHELOR, JG ;

ALBRAND, JP ;

ROBERTS, GCK .

JOURNAL OF MAGNETIC RESONANCE, 1979, 33 (03) :519-529