Benzylfluorocarbene: Reactions and kinetics

被引：7

作者：

Moss, RA

Maksimovic, L

Merrer, DC

机构：

[1] Department of Chemistry, Rutgers, Stt. Univ. of New Jersey, New Brunswick

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(97)01709-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzylfluorocarbene, generated from the corresponding diazirine, is accompanied by considerable azine formation. Its rearrangement to beta-fluorostyrene isomers in tetrachloroethane is characterized by E-a = 3.2 kcal/mol and log A = 9.5(s-1) (C) 1997 Elsevier Science Ltd.

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收藏

页码：7049 / 7052

页数：4

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