Chemical reduction of graphene oxide using green reductants

被引:455
作者
De Silva, K. K. H. [1 ]
Huang, H. -H. [1 ]
Joshi, R. K. [2 ]
Yoshimura, M. [1 ]
机构
[1] Toyota Technol Inst, Grad Sch Engn, Tempaku Ku, 2-12-1 Hisakata, Nagoya, Aichi 4688511, Japan
[2] Univ New South Wales, Sch Mat Sci & Engn, Ctr Sustainable Mat Res & Technol SMaRT, Sydney, NSW 2052, Australia
关键词
Graphene oxide; Green reductants; Ascorbic acid; Contents; FRIENDLY METHOD; REDUCING AGENT; VITAMIN-C; ACID;
D O I
10.1016/j.carbon.2017.04.025
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
Graphene has exceptional physical, chemical, mechanical, thermal and optical properties which offer huge potential for applications in various sectors. Chemical oxidation of graphite to graphene oxide followed by the reduction process is the commonly used method for mass scale production of graphene or reduced graphene oxide (RGO). Among the large number of chemical reducing agents used to prepare RGO or graphene, the most efficient reductant is hydrazine. It is toxic in nature and harmful to the environment, thus it is in high demand to use green reductants for RGO synthesis. We understand that due to high demand of graphene/graphene oxide/reduced graphene oxide recently and which is expected to be more in future, green synthesis methods are extremely important. In this article, we have studied the synthesis methods, characterization and the possible mechanism for green reduction, especially by ascorbic acid. This article could possibly motivate the researcher worldwide to innovate new green methods for mass scale production of graphene based materials. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:190 / 199
页数:10
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