Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies

被引：127

作者：

Corbett, JD ^{[1
]}

机构：

[1] IOWA STATE UNIV, AMES LAB, AMES, IA 50011 USA

来源：

STRUCTURAL AND ELECTRONIC PARADIGMS IN CLUSTER CHEMISTRY | 1997年 / 87卷

关键词：

metal polyhedra; hypoelectronic (clusters); naked clusters; electronic structure; synthesis; icosahedra; heavy metal clusters; centered clusters;

D O I：

10.1007/BFb0018034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Wade's rules provide valuable guidelines regarding geometric-electronic interrelations for over two dozen types of polyhedra among (1) Zintl ions of the group 14 and 15 elements isolated from nonaqueous solvents and (2) numerous anionic clusters of particularly In and T1 found in ''neat'' alkali-hypoelectronic, open-shell, and centered clusters and in networks are also described.

引用

页码：157 / 193

页数：37

共 113 条

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