Design of a radical translocation step through 1, n (n = 5, 6, 7) hydrogen transfers for incorporation into new radical cascades

被引：23

作者：

Gross, A

Fensterbank, L

Bogen, S

Thouvenot, R

Malacria, M

机构：

[1] UNIV PARIS 06,LAB CHIM ORGAN SYNTH,CNRS,F-75252 PARIS,FRANCE

[2] UNIV PARIS 06,LAB CHIM METAUX TRANSIT,CNRS,F-75252 PARIS,FRANCE

来源：

TETRAHEDRON | 1997年 / 53卷 / 40期

关键词：

D O I：

10.1016/S0040-4020(97)00899-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The scope and limitations in the 1,n (n = 5, 6, 7) hydrogen transfers from homoallyl radicals of type 10 have been delineated. Encouraging results have notably been obtained with a dioxolane on the side chain to promote a 1,6-H transfer and with a TBS ether to promote a 1,5-H transfer. (C) 1997 Elsevier Science Ltd.

引用

页码：13797 / 13810

页数：14

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[2]

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