Proton-conducting crystalline porous materials

被引：712

作者：

Meng, Xing ^{[1
,2
]}

Wang, Hai-Ning ^{[2
]}

Song, Shu-Yan ^{[1
]}

Zhang, Hong-Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Peoples R China

[2] Shandong Univ Technol, Coll Chem Engn, Zibo 255049, Shandong, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2017年 / 46卷 / 02期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; SULFONATE-CARBOXYLATE LIGANDS; COORDINATION POLYMERS; LAYER FRAMEWORK; DEGREES-C; ACID; MEMBRANES; MOF; COMPOSITE; POM;

D O I：

10.1039/c6cs00528d

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal organic frameworks (MOFs), coordination polymers (CPs), polyoxometalates (POMs) and covalent organic frameworks (COFs). The designable structures and high surface areas of these materials provide great opportunities to orderly accommodate proton carriers and to systemically modify the concentration and mobility of proton carriers in available spaces. Based on the understanding of the relationship between the structure and proton conductivity, controllable synthesis of porous materials with high proton conductivity will gradually be achieved. This review summarizes the emerging studies of these materials and their unique proton conductivities.

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收藏

页码：464 / 480

页数：17

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