Preparation and reactions of acylzinc species

被引：7

作者：

Chemla, F

Normant, JF

机构：

[1] Lab. de Chim. des Organo-Elements, URA 473 CNRS, Univ. Pierre et Marie Curie, 75252 Paris Cedex 05, 4, Place Jussieu

来源：

TETRAHEDRON | 1997年 / 53卷 / 51期

关键词：

D O I：

10.1016/S0040-4020(97)10179-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of acyl chlorides by zerovalent zinc dust is described. The reaction gives enol esters of (Z) configuration in high yields. The initial product is presumed to be an acyl zinc species, which gives the enol ester in a stereospecific manner by a 1,2-hydrogen shift on the carbene intermediate. (C) 1997 Elsevier Science Ltd.

引用

页码：17265 / 17274

页数：10

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