PREPARATION OF POLYFUNCTIONAL KETONES BY A COBALT(II) MEDIATED CARBONYLATION OF ORGANOZINC REAGENTS

被引:25
作者
DEVASAGAYARAJ, A [1 ]
KNOCHEL, P [1 ]
机构
[1] UNIV MARBURG, FACHBEREICH CHEM, D-35032 MARBURG, GERMANY
关键词
D O I
10.1016/0040-4039(95)01802-O
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Functionalized organozinc halides can be efficiently carbonylated under atmospheric pressure in the presence of cobalt(ll) bromide in THF:NMP leading to polyfunctional symmetrical ketones in 56-80% yield.
引用
收藏
页码:8411 / 8414
页数:4
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