Recent advances and future aspects in the selective isomerization of high n-alkanes

被引:230
作者
Akhmedov, Vagif M. [1 ]
Al-Khowaiter, Soliman H. [1 ]
机构
[1] Petr & Petrochem Res Inst, Riyadh 11442, Saudi Arabia
来源
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2007年 / 49卷 / 01期
关键词
high n-alkanes; waxy n-paraffins; isomerization; hydrocracking; solid acids; zeolite-base catalysts; zirconia-based catalysts; molecular sieves; shape selectivity;
D O I
10.1080/01614940601128427
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This article provides an overview of the advances that have been marked during the last decades in the field of hydroconversion of high n-alkanes (C-7(+)) with particular stress on the promising ways to meet the requirements for improved quality of motor fuels and oils. Particular attention is given to a catalyst formulation for selective conversion of high n-alkanes to branched hydrocarbons. The challenge for successfully solving this problem is to find an effective catalyst favoring the isomerization of n-alkanes without too much cracking. The regulation of active sites and adsorption properties, as well as the topology of support surfaces, allows a more predictive design of novel catalysts for selective conversion of high n-alkanes into their branched isomers.
引用
收藏
页码:33 / 139
页数:107
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