Electrochemical polymerization of 3,4-ethylenedioxythiophene in aqueous micellar solution containing biocompatible amino acid-based surfactant

被引：51

作者：

Wen, Yangping ^{[1
,2
]}

Xu, Jingkun ^{[1
]}

He, Haohua ^{[2
]}

Lu, Baoyang ^{[1
]}

Li, Yuzhen ^{[1
]}

Dong, Bin ^{[1
]}

机构：

[1] Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China

[2] Jiangxi Agr Univ, Minist Educ & Jiangxi Prov, Key Lab Crop Physiol Ecol & Genet Breeding, Nanchang 330045, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2009年 / 634卷 / 01期

关键词：

Conducting polymers; Poly(3,4-ethylenedioxythiophene); Electrochemical polymerization; Amino acid-based surfactant; Sodium N-lauroylsarcosinate; SODIUM DODECYL-SULFATE; CONDUCTING POLYMERS; POLY(3,4-ETHYLENEDIOXYTHIOPHENE) FILMS; OPTICAL-PROPERTIES; ORDERED SYSTEMS; ELECTROPOLYMERIZATION; POLYPYRROLE; GROWTH; ELECTRODEPOSITION; PEDOT;

D O I：

10.1016/j.jelechem.2009.07.012

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Poly(3,4-ethylenedioxythiophene) (PEDOT) films were synthesized electrochemically by direct anodic oxidation of 3,4-ethylenedioxythiophene (EDOT) in aqueous solution containing the environmentally-friendly amino acid-based surfactant sodium N-lauroylsarcosinate (SLS), which as a mild biosurfactant has good biocompatibility, low toxicity, good solubilization, and efficient and quick biodegradability. The moderate interactions between a neutral SLS-aqueous micellar solution and EDOT monomer led to the decreased onset oxidation potential of EDOT. PEDOT films were characterized spectroscopically using Fourier transform infrared and ultraviolet-visible techniques. PEDOT films with good thermal stability and electrical conductivity of 5 S cm(-1) were synthesized in neutral SLS-water micellar solutions. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：49 / 58

页数：10

共 59 条

[1] Biomolecular immobilization on conducting polymers for biosensing applications [J].

Ahuja, Tarushee ;

Mir, Irfan Ahmad ;

Kumar, Devendra ;

Rajesh .

BIOMATERIALS, 2007, 28 (05) :791-805

[2] Trends and challenges in biochemical sensors for clinical and environmental monitoring [J].

Andreescu, S ;

Sadik, OA .

PURE AND APPLIED CHEMISTRY, 2004, 76 (04) :861-878

[3] THE APPLICATION OF CONDUCTING POLYMERS IN BIOSENSORS [J].

BARTLETT, PN ;

BIRKIN, PR .

SYNTHETIC METALS, 1993, 61 (1-2) :15-21

[4] Study of poly(3,4-ethylenedioxythiophene) films prepared in propylene carbonate solutions containing different lithium salts [J].

Blanchard, F ;

Carré, B ;

Bonhomme, F ;

Biensan, P ;

Pagès, H ;

Lemordant, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 569 (02) :203-210

[5]

Chen Q, 1999, CHINESE CHEM LETT, V10, P789

[6] Poly(3,4-ethylenedioxythiophene) nanoparticles prepared in aqueous DBSA solutions [J].

Choi, JW ;

Han, MG ;

Kim, SY ;

Oh, SG ;

Im, SS .

SYNTHETIC METALS, 2004, 141 (03) :293-299

[7] Amino acid-based surfactants:: Enzymatic synthesis, properties and potential applications [J].

Clapés, P ;

Infante, MR .

BIOCATALYSIS AND BIOTRANSFORMATION, 2002, 20 (04) :215-233

[8]

DOWNARD AJ, 1986, J ELECTROANAL CHEM, V206, P139, DOI 10.1016/0022-0728(86)90263-9

[9] Effects of polymerization potential on the properties of electrosynthesized PEDOT films [J].

Du, X ;

Wang, Z .

ELECTROCHIMICA ACTA, 2003, 48 (12) :1713-1717

[10]

Fromherz P, 2002, CHEMPHYSCHEM, V3, P276, DOI 10.1002/1439-7641(20020315)3:3<276::AID-CPHC276>3.0.CO

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