Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform

被引：197

作者：

Bigi, Julian P. ^{[1
,2
]}

Hanna, Tamara E. ^{[1
,2
]}

Harman, W. Hill ^{[1
,2
]}

Chang, Alicia ^{[1
]}

Chang, Christopher J. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

[3] Univ Calif Berkeley, Howard Hughes Med Inst, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 06期

关键词：

FERRIC METHOXIDE COMPLEX; IRON-ONLY HYDROGENASE; RATE-DETERMINING STEP; H BOND ACTIVATION; ACTIVE-SITE; CRYSTAL-STRUCTURE; MOLECULAR CATALYSTS; LOW OVERPOTENTIALS; HYDROXIDE COMPLEX; FUNCTIONAL MODELS;

D O I：

10.1039/b915846d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cobalt(II) complex supported by the new tetradentate polypyridyl ligand PY4 is an electrocatalyst for the reduction of protons to hydrogen and can operate in 50% aqueous media.

引用

页码：958 / 960

页数：3

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