Treatment of brines by combined Fenton's reagent-aerobic biodegradation II.: Process modelling

被引:35
作者
Rivas, FJ [1 ]
Beltrán, FJ [1 ]
Gimeno, O [1 ]
Alvarez, P [1 ]
机构
[1] Univ Extremadura, Dept Ingn Quim & Energet, Badajoz 06071, Spain
关键词
brines; Fenton's reagent; aerobic biodegradation; table olive wastewater; modelling;
D O I
10.1016/S0304-3894(02)00216-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Process modelling of the integrated Fenton's reagent-aerobic biodegradation system has been carried out by considering a detailed reaction mechanism for the chemical oxidation step and the generalised Monod equation for the biological treatment. Chemical oxygen demand has been contemplated as a pseudo-component for simulation purposes. The proposed mechanism takes into consideration different features experimentally found. Thus, the inefficient hydrogen peroxide decomposition into oxygen and water, the influence of temperature and other operating variables and the role of oxygen have been considered. The aerobic biodegradation of the effluent after the chemical oxidation has taken place has been well simulated by Monod equation with no inhibitory terms. Dependency on temperature has been correlated by Arrhenius expression. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:259 / 276
页数:18
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