Association of hydrophobically end-capped poly(ethylene oxide)

被引：130

作者：

Chassenieux, C ^{[1
]}

Nicolai, T ^{[1
]}

Durand, D ^{[1
]}

机构：

[1] UNIV MAINE,UMR CNRS,F-72017 LE MANS,FRANCE

来源：

MACROMOLECULES | 1997年 / 30卷 / 17期

关键词：

D O I：

10.1021/ma970354j

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The associative character of poly(ethylene oxide) (PEO) end-capped with dodecyl groups was studied by using static and dynamic light scattering and viscometry. The effect of functionalization is investigated by comparing results on unmodified PEO with PEO of the same molar mass end-capped at one or both ends. The molar mass dependence is investigated by comparing difunctionalized PEO samples with different molar masses: 10, 20, and 35 kg/mol. The experimental data are well described by a crude model which assumes open association and incorporates interparticle interaction.

引用

页码：4952 / 4958

页数：7

共 23 条

[11] DYNAMICS OF ENTANGLED POLYMER-SOLUTIONS .1. ROUSE MODEL [J].