Synthesis and characterization of high-nuclearity osmium-rhodium mixed-metal carbonyl clusters; molecular and crystal structures of [Os12Rh9(CO)(44)(mu(3)-Cl)]center dot 2CH(2)Cl(2) and [Os4Rh3(mu(3)-H)(CO)(14)(mu(3)-CO)(eta(4)-C7H8)(2)]

被引：11

作者：

Hung, SYW ^{[1
]}

Wong, WT ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 21期

关键词：

D O I：

10.1039/a706080g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The anionic triosmium cluster EN(PPh3)2][Os-3(mu-H>(CO)(11)] reacts with [Rh(nbd)Cl)(2) (nbd = norbornadiene) in the presence of AgPF6 to give two new high-nuclearity;osmium-rhodium clusters [Os12Rh9(CO)(44)(mu(3)-Cl)] 1 and [OS4Rh3(mu(3)- H)(CO)(14)(mu(3)-CO)(eta(4)-C7H8)(2)] 2 in moderate yields.

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页码：2099 / 2100

页数：2

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