All-optical poling properties of new nonlinear fluorene derivatives

被引:8
作者
Apostoluk, Aleksandra
Nunzi, Jean-Michel [1 ]
Perepichka, Igor F.
Stepanenko, Zorislav V.
Serebryakov, Igor M.
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Queens Univ, Dept Phys, Kingston, ON K7L 3N6, Canada
[3] Univ Angers, CNRS, UMR 6136, Lab Proprites Opt Mat & Applicat, F-49045 Angers, France
[4] Inst Natl Sci Appl, CNRS, UMR 5511, Lab Phys Mat, F-69621 Villeurbanne, France
[5] Univ Durham, Dept Chem, Durham DH1 3LE, England
[6] Donetsk Natl Univ, Dept Chem, UA-83055 Donetsk, Ukraine
[7] Natl Acad Sci Ukraine, LM Litvinenko Inst Phys Organ & Coal Chem, UA-83114 Donetsk, Ukraine
关键词
all-optical poling; second-order nonlinear optical susceptibility; second harmonic generation; photoactive polymer films;
D O I
10.1016/j.chemphys.2006.11.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The polar orientation of fluorene-derivative molecules incorporated in a photoconducting polymer host is studied by means of all-optical poling. We investigate the influence of the donor and acceptor moieties on the induced polar order, we characterize the dynamics of the orientation process and suggest photoinduced reaction schemes by which an efficient all-optical poling is achieved. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:339 / 345
页数:7
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