Synthesis of Interlocked 56-Membered Rings by Dynamic Self-Templating

被引:37
作者
Chung, Mee-Kyung [1 ]
White, Peter S. [1 ]
Lee, Stephen J. [2 ]
Gagne, Michel R. [1 ]
机构
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[2] USA, Res Off, Res Triangle Pk, NC 27709 USA
关键词
molecular recognition; self-assembly; supramolecular chemistry; template synthesis; COMBINATORIAL LIBRARIES; SUPRAMOLECULAR CHEMISTRY; PEPTIDES; PROTEINS; AMPLIFICATION; DISCOVERY; STABILITY; RECEPTOR; BONDS;
D O I
10.1002/anie.200903478
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A love of self : Narcissistic macro cyclic rings self-assemble into highly ordered chiral [2]-catenanes displaying high component diastereoselectivity. The picture shows one such structure. One ring is shown in a space-filling representation (C green, O red, N blue, H gray), while other is shown as orange sticks © 2009 Wiley-VCH Verlag GmbH &. Co. KCaA.
引用
收藏
页码:8683 / 8686
页数:4
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