Performance of a novel type of electrolyte-supported solid oxide fuel cell with honeycomb structure

被引:26
作者
Carlos Ruiz-Morales, Juan [1 ]
Marrero-Lopez, David [2 ]
Pena-Martinez, Juan [3 ]
Canales-Vazquez, Jesus [3 ]
Josep Roa, Joan [4 ]
Segarra, Merce [4 ]
Savvin, Stanislav N. [1 ]
Nunez, Pedro [1 ]
机构
[1] Univ La Laguna, Dept Quim Inorgan, Tenerife 38200, Spain
[2] Univ Malaga, Dept Fis Aplicada 1, E-29071 Malaga, Spain
[3] Univ Castilla La Mancha, Inst Energias Renovables, Albacete 02006, Spain
[4] DIOPMA, Dept Ciencia Mat & Ing Met, Barcelona 08028, Spain
关键词
SOFC; Honeycomb structure; Hexagonal cells; NiO-YSZ composite; MECHANICAL-PROPERTIES; SOFC; ANODE;
D O I
10.1016/j.jpowsour.2009.08.017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel design, alternative to the conventional electrolyte-supported solid oxide fuel cell (SOFC) is presented. In this new design, a honeycomb-electrolyte is fabricated from hexagonal cells, providing high mechanical strength to the whole structure and supporting the thin layer used as electrolyte of a SOFC. This new design allows a reduction of similar to 70% of the electrolyte material and it renders modest performances over 320 mW cm(-2) but high volumetric power densities, i.e. 1.22 W cm(-3) under pure CH(4) at 900 degrees C, with a high OCV of 1.13 V, using the standard Ni-YSZ cermet as anode, Pt as cathode material and air as the oxidant gas. (C) 2009 Elsevier B. V. All rights reserved.
引用
收藏
页码:516 / 521
页数:6
相关论文
共 19 条
[1]  
Appleby A.J., 1989, FUEL CELL HDB
[2]   On the simultaneous use of La0.75Sr0.25Cr0.5Mn0.5O3-δ as both anode and cathode material with improved microstructure in solid oxide fuel cells [J].
Carlos Ruiz-Morales, Juan ;
Canales-Vazquez, Jesus ;
Pena-Martinez, Juan ;
Marrero-Lopez, David ;
Nunez, Pedro .
ELECTROCHIMICA ACTA, 2006, 52 (01) :278-284
[3]  
Hertz H., 1882, J REINE ANGEW MATH, P156, DOI DOI 10.1515/CRLL.1882.92.156
[4]  
Matula G., 2008, Archives of Materials Science and Engineering, V32, P21
[5]   An examination of carbonaceous deposits in direct-utilization SOFC anodes [J].
McIntosh, S ;
He, HP ;
Lee, SI ;
Costa-Nunes, O ;
Krishnan, VV ;
Vohs, JM ;
Gorte, RJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (04) :A604-A608
[6]  
Minh N.Q., 1995, SCI TECHNOLOGY CERAM
[7]  
Mistler R.E., 2000, TAPE CASTING THEORY
[8]  
Primdahl S., 1999, THESIS U TWENTE NETH
[9]   Mechanical properties of tape cast nickel-based anode materials for solid oxide fuel cells before and after reduction in hydrogen [J].
Radovic, M ;
Lara-Curzio, E .
ACTA MATERIALIA, 2004, 52 (20) :5747-5756
[10]   Cost-Effective Microstructural Engineering of Solid Oxide Fuel Cell Components for Planar and Tubular Designs [J].
Ruiz-Morales, Juan Carlos ;
Pena-Martinez, Juan ;
Canales-Vazquez, Jesus ;
Marrero-Lopez, David ;
Savaniu, Cristian ;
Nunez, Pedro .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (01) :276-279