Thermodynamics of intercalation in C-60 fullerite and stability of cubic close-packed fulleride compounds

被引：8

作者：

Claves, D ^{[1
]}

Touzain, P ^{[1
]}

机构：

[1] UNIV GRENOBLE 1,DEPT CHIM,IUT1,F-38000 GRENOBLE,FRANCE

来源：

SYNTHETIC METALS | 1996年 / 80卷 / 03期

关键词：

fullerene; thermodynamics; intercalation;

D O I：

10.1016/0379-6779(96)80218-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Stability of known or hypothetical fullerene C-60 intercalation compounds was investigated through a donor-acceptor scheme. A thermodynamic cycle was employed, requiring evaluation of energy costs related with charge transfer and formation of the intercalated solid. Strongly exothermic reactions are predicted in several cases, especially with some elements of the rare-earth series, which should consequently form stable, low dimensional phases. These latter might be interesting candidates for superconductivity, as alkali-doped C-60.

引用

页码：301 / 307

页数：7

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