Synthesis of palladium icosahedra with twinned structure by blocking oxidative etching with citric acid or citrate ions

被引：248

作者：

Xiong, Yujie

McLellan, Joseph M.

Yin, Yadong

Xia, Younan ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

[2] Lawrence Berkeley Lab, Mol Foundry, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 05期

关键词：

citrate; etching; icosahedra; nanostructures; palladium;

D O I：

10.1002/anie.200604032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A remedy for etching: Citric acid and citrate ion were used to prevent oxidative etching from the reaction system by taking advantage of their strong binding to Pd surfaces. This method allowed Pd icosahedra (see picture) to be formed in yields as high as 80%. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：790 / 794

页数：5

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