Synthesis of palladium icosahedra with twinned structure by blocking oxidative etching with citric acid or citrate ions

被引：248

作者：

Xiong, Yujie

McLellan, Joseph M.

Yin, Yadong

Xia, Younan ^{[1
]}

机构：

[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA

[2] Lawrence Berkeley Lab, Mol Foundry, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 05期

关键词：

citrate; etching; icosahedra; nanostructures; palladium;

D O I：

10.1002/anie.200604032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A remedy for etching: Citric acid and citrate ion were used to prevent oxidative etching from the reaction system by taking advantage of their strong binding to Pd surfaces. This method allowed Pd icosahedra (see picture) to be formed in yields as high as 80%. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：790 / 794

页数：5

共 37 条

[11] Formation of colloidal silver nanoparticles: Capping action of citrate
Henglein, A
Giersig, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (44): : 9533 - 9539
[12] Reduction of Pt(II) by H2:: Effects of citrate and NaOH and reaction mechanism
Henglein, A
Giersig, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (29): : 6767 - 6772
[13] Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance
Hirsch, LR
Stafford, RJ
Bankson, JA
Sershen, SR
Rivera, B
Price, RE
Hazle, JD
Halas, NJ
West, JL
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (23) : 13549 - 13554
[14] Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio
Jana, NR
Gearheart, L
Murphy, CJ
[J]. CHEMICAL COMMUNICATIONS, 2001, (07) : 617 - 618
[15] SURFACE RAMAN SPECTROELECTROCHEMISTRY .1. HETEROCYCLIC, AROMATIC, AND ALIPHATIC-AMINES ADSORBED ON ANODIZED SILVER ELECTRODE
JEANMAIRE, DL
VANDUYNE, RP
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1977, 84 (01) : 1 - 20
[16] The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment
Kelly, KL
Coronado, E
Zhao, LL
Schatz, GC
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (03) : 668 - 677
[17] Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for Suzuki coupling reactions
Kim, SW
Kim, M
Lee, WY
Hyeon, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (26) : 7642 - 7643
[18] Kreibig U., 1995, OPTICAL PROPERTIES M, V25
[19] Suzuki cross-coupling reactions catalyzed by palladium nanoparticles in aqueous solution
Li, Y
Hong, XM
Collard, DM
El-Sayed, MA
[J]. ORGANIC LETTERS, 2000, 2 (15) : 2385 - 2388
[20] Surface-enhanced Raman scattering of 4-mercaptopyridine on thin films of nanoscale Pd cubes, boxes, and cages
McLellan, JM
Xiong, YJ
Hu, M
Xia, YN
[J]. CHEMICAL PHYSICS LETTERS, 2006, 417 (1-3) : 230 - 234

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