anti-[2.2](1,4)phthalocyaninophane:: Spectroscopic evidence for transannular interaction in the excited states

被引：40

作者：

Asano, Yoshiaki

Muranaka, Atsuya

Fukasawa, Akira

Hatano, Terutaka

Uchiyama, Masanobu

Kobayashi, Nagao ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

[3] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 15期

关键词：

D O I：

10.1021/ja068528c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and synthesis of a novel type of bisphthalocyanines, anti-[2.2](1,4)phthalocyaninophanes, were reported. The phthalocyanine dimer exhibited significantly split and red-shifted absorption in the near-IR region and maintained the fluorescence properties of phthalocyanines. The origin of the electronic communication between the two phthalocyanines was rationalized on the basis of the MO model analysis.

引用

页码：4516 / +

页数：3

共 21 条

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