A hexacarbene complex derived from 1,1′-methylenebis(4-butyl-1H-1,2,4-triazolium) diiodide.: Synthesis, characterization and catalytic activity

被引：19

作者：

Díez-Barra, E ^{[1
]}

Guerra, J ^{[1
]}

Rodríguez-Curiel, RI ^{[1
]}

Merino, S ^{[1
]}

Tejeda, J ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Quim, Ciudad Real, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 660卷 / 01期

关键词：

1,2,4-triazole-5-ylidene; carbene; palladium; catalysis;

D O I：

10.1016/S0022-328X(02)01730-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of a hexacarbene complex (1) derived from 1,1'-methylenebis(4-butyl-1H-1,2,4-triazolium) diiodide are reported. The organic backbone was constructed prior to the introduction of metal atoms by reaction with palladium(II) acetate. The catalytic activity of 1 in a Heck reaction has been tested. (C) 2002 Elsevier Science B. V. All rights reserved.

引用

页码：50 / 54

页数：5

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