Ti-pillared clays: Synthesis and general characterization

被引：32

作者：

Romero, Amaya ^{[1
]}

Dorado, Fernando ^{[1
]}

Asencio, Isaac ^{[1
]}

Belen Garcia, Prado ^{[1
]}

Luis Valverde, Jost ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Dept Ingn Quim, Fac Quim, Escuela Univ Ingn Tecn Agr, Ciudad Real 13004, Spain

来源：

CLAYS AND CLAY MINERALS | 2006年 / 54卷 / 06期

关键词：

alkoxide; clays; PILCs; review; synthesis; TiCl4; titanium;

D O I：

10.1346/CCMN.2006.0540608

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review is concerned with the synthesis and physical-chemical characteristics of a specific type of modified clay material: Ti-PILCs. The two general synthetic procedures and the main problems associated with the scale-up synthesis of these pillared materials are discussed in detail. The general characteristics of Ti-PILCs in terms of basal spacing, pillar homogeneity, surface area, microporosity, mesoporosity, pore size and distribution, thermal resistance and acidity are discussed in depth. Likewise, the most important synthesis parameters that have a clear and marked influence on the final characteristics of the materials are summarized.

引用

页码：737 / 747

页数：11

共 113 条

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