Fine particle formation using supercritical fluids

被引:152
作者
Hakuta, Y [1 ]
Hayashi, H [1 ]
Arai, K [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, AIST, Supercrit Fluid Res Ctr, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
supercritical fluids; particle formation; micronization; hydrothermal synthesis;
D O I
10.1016/j.cossms.2003.12.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The use of supercritical fluids as solvents for the formation of micro- and nano-particles has shown tremendous over the past few years due to increased demands from industry for materials with high performance specifications and high or unique functionality. Supercritical fluids allow synthesis of many types of particles since the solvent's chemical and physical properties can be varied with temperature or pressure, both of which can affect the degree of supersaturation and nucleation. In this review, we describe methods for the formation of fine particles using supercritical fluids CO2 and water. Basic principles and specific features of each solvent are described, and the advantages and limitations are discussed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:341 / 351
页数:11
相关论文
共 160 条
[1]   Texture and nanostructure of chromia aerogels prepared by urea-assisted homogeneous precipitation and low-temperature supercritical drying [J].
Abecassis-Wolfovich, M ;
Rotter, H ;
Landau, MV ;
Korin, E ;
Erenburg, AI ;
Mogilyansky, D ;
Gartstein, E .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2003, 318 (1-2) :95-111
[2]  
ADAMI R, 2003, P 6 INT S SUP FLUIDS, V3, P1753
[3]  
ADAMI R, 2003, P 6 INT S SUP FLUID, V3, P1623
[4]  
ADSCHIRI T, 2003, P 6 INT S SUP FLUID, V2, P1237
[5]  
AZEVEDO EG, 2003, P 6 INT S SUP FLUIDS, V3, P1859
[6]  
BARILLARO V, 2003, P 6 INT S SUP FLUID, V3, P1897
[7]   Using CO2 to produce chemical products sustainably [J].
Beckman, EJ .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (17) :347A-353A
[8]  
BEGUT G, 2003, P 6 INT S SUP FLUID, V3, P1807
[9]   Thermal and morphological characterisation of micronized acetylsalicylic acid powders prepared by rapid expansion of a supercritical solution [J].
Bettini, R ;
Rossi, A ;
Lavezzini, E ;
Frigo, E ;
Pasquali, I ;
Giordano, F .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 73 (02) :487-497
[10]   Effect of concentration and degree of saturation on RESS of a CO2-soluble fluoropolymer [J].
Blasig, A ;
Shi, CM ;
Enick, RM ;
Thies, MC .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (20) :4976-4983