Fine particle formation using supercritical fluids

被引:152
作者
Hakuta, Y [1 ]
Hayashi, H [1 ]
Arai, K [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, AIST, Supercrit Fluid Res Ctr, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
supercritical fluids; particle formation; micronization; hydrothermal synthesis;
D O I
10.1016/j.cossms.2003.12.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The use of supercritical fluids as solvents for the formation of micro- and nano-particles has shown tremendous over the past few years due to increased demands from industry for materials with high performance specifications and high or unique functionality. Supercritical fluids allow synthesis of many types of particles since the solvent's chemical and physical properties can be varied with temperature or pressure, both of which can affect the degree of supersaturation and nucleation. In this review, we describe methods for the formation of fine particles using supercritical fluids CO2 and water. Basic principles and specific features of each solvent are described, and the advantages and limitations are discussed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:341 / 351
页数:11
相关论文
共 160 条
[81]  
MARONGIU B, 2003, P 6 INT S SUP FLUID, V3, P1903
[82]   Effect of organic solvents on membrane formation by phase separation with supercritical CO2 [J].
Matsuyama, H ;
Yamamoto, A ;
Yano, H ;
Maki, T ;
Teramoto, M ;
Mishima, K ;
Matsuyama, K .
JOURNAL OF MEMBRANE SCIENCE, 2002, 204 (1-2) :81-87
[83]   Microencapsulation of TiO2 nanoparticles with polymer by rapid expansion of supercritical solution [J].
Matsuyama, K ;
Mishima, K ;
Hayashi, K ;
Matsuyama, H .
JOURNAL OF NANOPARTICLE RESEARCH, 2003, 5 (1-2) :87-95
[84]   Formation of microcapsules of medicines by the rapid expansion of a supercritical solution with a nonsolvent [J].
Matsuyama, K ;
Mishima, K ;
Hayashi, KI ;
Ishikawa, H ;
Matsuyama, H ;
Harada, T .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 89 (03) :742-752
[85]   Synthesis and stabilization of silver metallic nanoparticles and premetallic intermediates in perfluoropolyether/CO2 reverse micelle systems [J].
McLeod, MC ;
McHenry, RS ;
Beckman, EJ ;
Roberts, CB .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (12) :2693-2700
[86]   Protein-conjugated nanoparticles from rapid expansion of supercritical fluid solution into aqueous solution [J].
Meziani, MJ ;
Sun, YP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (26) :8015-8018
[87]   Protein-protected nanoparticles from rapid expansion of supercritical solution into aqueous solution [J].
Meziani, MJ ;
Rollins, HW ;
Allard, LF ;
Sun, YP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (43) :11178-11182
[88]   Influence of synthetic and processing parameters on the surface area, speciation, and particle formation in copper oxide/silica aerogel composites [J].
Mohanan, JL ;
Brock, SL .
CHEMISTRY OF MATERIALS, 2003, 15 (13) :2567-2576
[89]   Study of the solid state of carbamazepine after processing with gas anti-solvent technique [J].
Moneghini, M ;
Kikic, I ;
Voinovich, D ;
Perissutti, B ;
Alessi, P ;
Cortesi, A ;
Princivalle, F ;
Solinas, D .
EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS, 2003, 56 (02) :281-289
[90]   Sol-gel route to direct formation of silica aerogel microparticles using supercritical solvents [J].
Moner-Girona, M ;
Roig, A ;
Molins, E ;
Llibre, J .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :645-649