A new, practical access to amidyl radicals

被引：49

作者：

Moutrille, C ^{[1
]}

Zard, SZ ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, Synth Organ Lab, F-91128 Palaiseau, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 16期

关键词：

D O I：

10.1039/b405545d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.

引用

页码：1848 / 1849

页数：2

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