Identification of defect sites on MgO(100) surfaces

被引：20

作者：

Kim, YD ^{[1
]}

Stultz, J ^{[1
]}

Goodman, DW ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

LANGMUIR | 2002年 / 18卷 / 10期

关键词：

D O I：

10.1021/la0117799

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methodologies are reported that allow the identification of extended defects on MgO(100) surfaces. The techniques used include low-energy electron diffraction (LEED), metastable impact electron spectroscopy (MIES), D2O and CO temperature-programmed desorption (TPD), and MIES of adsorbed Xe. LEED and MIES data for MgO(100), TPD spectra of D2O and CO, and MIES spectra for adsorbed Xe are significantly altered as a function of the density of the extended defects. NO is shown to be an ineffective probe molecule for titration of defect sites on MgO(100).

引用

页码：3999 / 4004

页数：6

共 24 条

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