Heterogenised iridium complexes for the asymmetric hydrogenation of imines

被引：35

作者：

Margalef-Catalá, R ^{[1
]}

Claver, C ^{[1
]}

Salagre, P ^{[1
]}

Fernández, E ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)00105-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A method for immobilising preformed chiral homogeneous catalysts to a clay support material has been developed. The observed asymmetric induction in the hydrogenation of imines with the supported species was greater than that with the corresponding homogeneous catalysts and, on re-use, the supported species increased their enantioselectivity. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1469 / 1476

页数：8

共 37 条

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