A model for heap bioleaching of chalcocite with heat balance: Mesophiles and moderate thermophiles

被引:53
作者
Leahy, M. J. [1 ]
Davidson, M. R.
Schwarz, M. P.
机构
[1] CSIRO Minerals, Clayton, Vic 3168, Australia
[2] Univ Melbourne, Dept Chem & Biomol Engn, Parkville, Vic 3010, Australia
关键词
thermophiles; mesophiles; heap bioleaching; chalcocite ores; modelling; reaction kinetics; computational fluid dynamics; FERROUS SULFATE; OXIDATION; BACTERIA; CHALCOPYRITE; FERROOXIDANS; TEMPERATURE; TRANSPORT; IRON; PH;
D O I
10.1016/j.hydromet.2006.07.004
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The interaction of mesophiles and moderate thermophiles (MT) in a 3-pbase computational fluid dynamics model for heap bioleaching of chalcocite is investigated. The model assumes that both bacterial types undergo the same death, attachment and detachment processes, with different growth rate temperature dependency. The model allows an investigation of bow the bacterial types vary in space and time as the conditions (such as the temperature) in the heap change. The model results are compared to the case with a single bacterial type (mesophiles) from previous work, showing that the bottom-up and top-down leaching fronts which develop in that case are also present here. The bottom-up leaching front is found to move faster than in the case with only mesophiles, and the leaching front from the top-down is slower here. Both these effects are due to the high temperature gradient in the heap (due to MT), and higher associated evaporation and condensation (and associated release or consumption of latent heat) across the respective leaching fronts. The addition of MT allows a longer period before overheating occurs, so that there is more leaching in the initial stage. The ambient temperature and inoculation method were varied to show the impact on leaching. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:24 / 41
页数:18
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