Catalysis of dendrimer-bound Pd(II) complex - Selective hydrogenation of conjugated dienes to monoenes

被引：54

作者：

Mizugaki, T ^{[1
]}

Ooe, M ^{[1
]}

Ebitani, K ^{[1
]}

Kaneda, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Sci & Chem Engn, Toyonaka, Osaka 5608531, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 145卷 / 1-2期

关键词：

diphenylphosphinomethylated dendrimer; dendrimer-bound Pd(II) complex; selective hydrogenation; conjugated dienes; catalyst reuse;

D O I：

10.1016/S1381-1169(99)00186-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Complexation of the diphenylphosphinomethylated dendrimer DAB-dendr-[N(CH2PPh2)(2)](16) with PdCl2(PhCN)(2) gave a dendrimer-bound PdCl2 complex. The dendritic Pd complex showed high catalytic activity for the selective hydrogenation of conjugated dienes to monoenes under mild reaction conditions. The catalytic activity of the dendritic Pd complex was higher than that of the corresponding low-molecular weight complex [PhN(CH2PPh2)(2)PdCl2]. The dendritic catalyst was easily recovered from reaction mixtures and could be reused without any loss of the activity. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：329 / 333

页数：5

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