NMR study on ligand exchange reaction between a chiral allylsilane and SnCl4

被引：21

作者：

Dias, LC ^{[1
]}

Meira, PRR ^{[1
]}

Ferreira, E ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, BR-13083970 Campinas, SP, Brazil

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 09期

关键词：

D O I：

10.1021/ol990869q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A spectroscopic (H-1,C-13, and Sn-119 NMR) study of the reaction of chiral allylsilane 1 with SnCl4 is described. We have found that the ligand exchange between SnCl4 and this allylsilane is instantaneous and quantitative at 25 degrees C as well as at -60 degrees C, affording the corresponding allyltrichlorostannane.

引用

页码：1335 / 1338

页数：4

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