Boron Clusters as Highly Stable Magnesium-Battery Electrolytes

被引：259

作者：

Carter, Tyler J. ^{[2
]}

Mohtadi, Rana ^{[1
]}

Arthur, Timothy S. ^{[1
]}

Mizuno, Fuminori ^{[1
]}

Zhang, Ruigang ^{[1
]}

Shirai, Soichi ^{[3
]}

Kampf, Jeff W. ^{[2
]}

机构：

[1] Toyota Res Inst North Amer, Mat Res Dept, Ann Arbor, MI 48105 USA

[2] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[3] Toyota Cent R&D, Nagakute, Aichi, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 12期

关键词：

carboranes; clusters; electrochemistry; magnesium; rechargeable batteries; ELECTROCHEMICAL-BEHAVIOR; ELECTRODES; SYSTEMS;

D O I：

10.1002/anie.201310317

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Boron clusters are proposed as a new concept for the design of magnesium-battery electrolytes that are magnesium-battery-compatible, highly stable, and noncorrosive. A novel carborane-based electrolyte incorporating an unprecedented magnesium-centered complex anion is reported and shown to perform well as a magnesium-battery electrolyte. This finding opens a new approach towards the design of electrolytes whose likelihood of meeting the challenging design targets for magnesium-battery electrolytes is very high.

引用

页码：3173 / 3177

页数：5

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