Simulation of dye adsorption on hydrolyzed wheat straw in batch and fixed-bed systems

被引:102
作者
Batzias, Fragiskos [1 ]
Sidiras, Dimitris [1 ]
Schroeder, Elisabeth [2 ]
Weber, Christina [2 ]
机构
[1] Univ Piraeus, Dept Ind Management & Technol, Lab Simulat Ind Proc, GR-18534 Piraeus, Greece
[2] Forschungszentrum Karlsruhe, Inst Fuer Kern & Energietech, D-76021 Karlsruhe, Germany
关键词
Basic dyes; Adsorption; Wheat straw; Acid hydrolysis; Column; BEECH SAWDUST; BASIC-DYES; ACTIVATED-CARBON; AQUEOUS-SOLUTION; ACID-HYDROLYSIS; METHYLENE-BLUE; REMOVAL; WASTE; WOOD; PERFORMANCE;
D O I
10.1016/j.cej.2008.09.025
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The simulation of batch and column kinetics of Methylene Blue and Red Basic 22 adsorption on mild acid hydrolyzed wheat straw was investigated, using untreated wheat straw as control, in order to examine its properties for potential use as a low cost adsorbent for wastewater dye removal. The BET surface area, the adsorption capacities (estimated according to Freundlich and Langmuir models), indicated that mild acid hydrolysis enhances significantly the adsorption properties of the original material. This enhancement can be attributed to the removal of the hemicelluloses during sulfuric acid treatment, resulting in the 'opening' of the pores of lignocellulosic matrix's structure and the increasing of the BET surface area. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:459 / 472
页数:14
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