Structural Parameters of Cu2+ Aqua Complexes in Aqueous Solutions of Its Salts

被引：20

作者：

Smirnov, P. R. ^{[1
]}

Trostin, V. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 08期

关键词：

MONTE-CARLO SIMULATIONS; X-RAY-DIFFRACTION; MOLECULAR-DYNAMICS SIMULATIONS; COPPER CHLORIDE SOLUTIONS; COORDINATION STRUCTURE; NEUTRON-DIFFRACTION; FINE-STRUCTURE; CU(II); IONS; WATER;

D O I：

10.1134/S1070363209080015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Published data of various research techniques and own experimental results obtained by the X-ray structural analysis concerning structural characteristics of copper(II) aqua complexes in aqueous solutions of its salts under standard conditions have been generalized. Structural parameters of the nearest environment of this ion, such as coordination number, interparticle distances, and ionic association types, were considered. The possibility of the Jahn-Teller effect realization in aqueous solutions Of Cu2+ salts was examined.

引用

页码：1591 / 1599

页数：9

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