Enantioselective tautomerization of a new metastable enol

被引：16

作者：

Henze, R

Duhamel, L

Lasne, MC

机构：

[1] UNIV ROUEN,INST RECH CHIM ORGAN FINE,CNRS,F-76821 MONT ST AIGNAN,FRANCE

[2] UNIV CAEN,ISMRA,CNRS,LAB CHIM MOL & THIOORGAN,F-14050 CAEN,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(97)00408-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new metastable enol was prepared by the reaction of 2-benzyl acrolein with thiobenzoic acid in aprotic solvents. The enantioselective tautomerization of this enol was studied and enantiomeric excesses up to 71% were found. The absolute configuration of the resulting aldehyde was assigned. (C) 1997 Elsevier Science Ltd.

引用

页码：3363 / 3365

页数：3