Structural diversity of peroxidase-catalyzed oxidation products of o-methoxyphenois

被引：37

作者：

Antoniotti, S

Santhanam, L

Ahuja, D

Hogg, MG

Dordick, JS

机构：

[1] Rensselaer Polytech Inst, Dept Chem & Biol Engn, Troy, NY 12180 USA

[2] Rensselaer Polytech Inst, Dept Biol, Troy, NY 12180 USA

[3] Vet Adm Med Ctr, Albany, NY 12208 USA

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 12期

关键词：

D O I：

10.1021/ol049448l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The biocatalylic oxidation of o-methoxyphenolic compounds led to a variety of oligophenols (dimers to pentamers) and some of their oxidation products. The reaction was carried out in an aqueous medium at room temperature with hydrogen peroxide as the terminal oxidant in a facile and green route to potentially bioactive compounds. Detailed structural information on the products of peroxidase-catalyzed oxidation of o-methoxyphenols is presented for the first time.

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页码：1975 / 1978

页数：4

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