The application of monodentate secondary phosphine oxide ligands in rhodium- and iridium-catalyzed asymmetric hydrogenation

被引：73

作者：

Jiang, XB

van den Berg, M

Minnaard, AJ

Feringa, BL

de Vries, JG

机构：

[1] Univ Groningen, Stratingh Inst, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands

[2] DSM Res & Patents, Life Sci Adv Synth & Catalysis, NL-6160 MD Geleen, Netherlands

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 14期

关键词：

D O I：

10.1016/j.tetasy.2004.05.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiopure secondary phosphine oxides have been tested as ligands in the rhodium- and iridium-catalyzed asymmetric hydrogenation of functionalized olefins. tert-Butylphosphinoyl benzene turned out to be a versatile ligand in the iridium-catalyzed hydrogenation of beta-branched dehydroamino esters and in the rhodium-catalyzed hydrogenation of an enol carbamate. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2223 / 2229

页数：7

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