2,2,4,4,6,6-Hexabenzylcyclotristannatellurane (Bn2SnTe)3.: Synthesis and structural characterization of an organometallic single-source precursor to phase-pure, polycrystalline SnTe

被引：32

作者：

Boudjouk, P ^{[1
]}

Remington, MP ^{[1
]}

Grier, DG ^{[1
]}

Triebold, W ^{[1
]}

Jarabek, BR ^{[1
]}

机构：

[1] N Dakota State Univ, Ctr Main Grp Chem, Dept Chem, Fargo, ND 58105 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 22期

关键词：

D O I：

10.1021/om990506u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, (Bn2SnTe)(3) Bn = CH2CsH5, was prepared in high yield by treating Bn2SnCl2 with (NH4)(2)Te. Details of the synthesis and characterization (H-1, C-13, Sn-119, and Te-125 NMR; IR, single-crystal XRD, and elemental analyses) are presented. (Bn2SnTe)(3) serves as an efficient single-source precursor to phase-pure cubic SnTe under mild conditions.

引用

页码：4534 / 4537

页数：4

共 36 条

[1]

Abrikosov N. K., 1969, Semiconducting II-VI, IV-VI and V-VI Compounds, DOI 10.1007/978-1-4899-6373-4

[2]

[Anonymous], 1986, B ALLOY PHASE DIAGR

[3]

Berger L. I., 1997, SEMICONDUCTOR MAT

[4] APPLICABILITY OF VEGARDS LAW TO PBXSN1-XTE ALLOY SYSTEM [J].

BIS, RF ;

DIXON, JR .

JOURNAL OF APPLIED PHYSICS, 1969, 40 (04) :1918-&

[5] 2,2,4,4,6,6-HEXAMETHYLCYCLOTRISTANNATELLURANE, A SN3TE3-RING WITH C-2-SYMMETRY [J].

BLECHER, A ;

DRAGER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (09) :677-677

[6] TIN-CHALCOGEN HETEROCYCLES .8. DIMETHYLTIN TELLURIDE, A 6-MEMBERED RING [J].

BLECHER, A ;

MATHIASCH, B .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (02) :246-246

[7]

BLITZ W, 1909, Z ANORG ALLG CHEM, V64, P226

[8] Benzyl-substituted tin chalcogenides. Efficient single-source precursors for tin sulfide, tin selenide, and Sn(SxSe1-x) solid solutions [J].

Boudjouk, P ;

Seidler, DJ ;

Grier, D ;

McCarthy, GJ .

CHEMISTRY OF MATERIALS, 1996, 8 (06) :1189-1196

[9] BIS(TRIPHENYLTIN) CHALCOGENIDES AS CONVENIENT PRECURSORS TO PHASE-PURE BINARY SEMICONDUCTORS [J].

BOUDJOUK, P ;

SEIDLER, DJ ;

BAHR, SR ;

MCCARTHY, GJ .

CHEMISTRY OF MATERIALS, 1994, 6 (11) :2108-2112

[10]

BOUDJOUK P, 1992, J CHEM MATER, V4, P383

← 1 2 3 4 →