2,2,4,4,6,6-Hexabenzylcyclotristannatellurane (Bn2SnTe)3.: Synthesis and structural characterization of an organometallic single-source precursor to phase-pure, polycrystalline SnTe

被引：32

作者：

Boudjouk, P ^{[1
]}

Remington, MP ^{[1
]}

Grier, DG ^{[1
]}

Triebold, W ^{[1
]}

Jarabek, BR ^{[1
]}

机构：

[1] N Dakota State Univ, Ctr Main Grp Chem, Dept Chem, Fargo, ND 58105 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 22期

关键词：

D O I：

10.1021/om990506u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, (Bn2SnTe)(3) Bn = CH2CsH5, was prepared in high yield by treating Bn2SnCl2 with (NH4)(2)Te. Details of the synthesis and characterization (H-1, C-13, Sn-119, and Te-125 NMR; IR, single-crystal XRD, and elemental analyses) are presented. (Bn2SnTe)(3) serves as an efficient single-source precursor to phase-pure cubic SnTe under mild conditions.

引用

页码：4534 / 4537

页数：4

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