Palladium complexes with Pd→B dative bonds:: Analysis of the bonding in the palladaboratrane compound [κ4-B(mimBut)3]Pd(PMe3)

被引：114

作者：

Pang, Keliang ^{[1
]}

Quan, Stephanie M. ^{[1
]}

Parkin, Gerard ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 48期

关键词：

D O I：

10.1039/b611654j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dinuclear complex {[mu-kappa(1), kappa(3)-B( mim (But))(3)]Pd}(2), which features a Pd -> B dative bond, may be obtained by the reaction of [Tm-But]K with Pd(OAc)(2); treatmentof {[mu-kappa(1), kappa(3)-B(mim(But))(3)]Pd}(2) with PMe3 affords the mononuclear boratrane derivative [kappa(4)-B(mim(But))(3)]Pd(PMe3), for which a molecular orbital analysis indicates that the palladium center possesses a d(8) configuration.

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页码：5015 / 5017

页数：3

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