Synthesis of copper(I) catenanes incorporating a disulfide bridge and their deposition on a gold surface

被引:36
作者
Raehm, L [1 ]
Hamann, C [1 ]
Kern, JM [1 ]
Sauvage, JP [1 ]
机构
[1] Lab Chim Organomin, UMR 7513, F-67000 Strasbourg, France
关键词
D O I
10.1021/ol005774z
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
GRAPHICS The synthesis of two coordinating catenates with the ability to undergo surface-confined chemistry is described, For each catenate, one of the rings includes a 2,9-diphenyl-1,10-phenanthroline unit as a coordinating moiety and a disulfide bridge, which allows adsorption of the catenate onto a gold surface, thus going from a molecular catenate to a [gold adsorbed] species in which gold atoms are elements of one of the rings.
引用
收藏
页码:1991 / 1994
页数:4
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