Ancillary ligand control of reactivity. Protonation at hydride vs cyanide in trans-[FeH(CN)(R(2)PCH(2)CH(2)PR(2))(2)] (R=Et, Ph, p-tolyl) and X-ray crystal structure determination of trans-[FeH(CNH)(R(2)PCH(2)CH(2)PR(2))2]BF4 (R=p-tolyl)

被引:24
作者
Amrhein, PI [1 ]
Drouin, SD [1 ]
Forde, CE [1 ]
Lough, AJ [1 ]
Morris, RH [1 ]
机构
[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA
关键词
D O I
10.1039/cc9960001665
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ancillary ligands in trans-[FeH(CN)L(2)] control whether protonation occurs at hydride to produce a dihydrogen complex or at cyanide to produce a hydrogen isocyanide complex.
引用
收藏
页码:1665 / 1666
页数:2
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